List of Publications
54. ChemXriv, 2025
Metallaaromaticity Reimagined: Metallaaromatic Cobalt Macrocycles Through Metal-Ligand Coordination Chemistry
Sakthi Raje, Katarzyna Młodzikowska-Pieńko, Amnon Stanger, Renana Gershoni-Poranne, and Graham de Ruiter
Read More202553. J. Am. Chem. Soc., 2025, In Press
An Experimental and Theoretical Investigation into [2π+2π] Cycloaddition Reactions Catalyzed by a Cationic Cobalt(I) Complex Containing a Strong-Field PCNHCP Pincer Ligand
Tofayel Sheikh Mohammad, Yi Jin, Sakthi Raje, Katarzyna Młodzikowska-Pieńko, Zhi-Xiang Yu, and Graham de Ruiter
Read More52. Angew. Chem. Int. Ed. 2025, e202423275
Manganese-Ketenimine Intermediates as Active Catalysts in the Michael Addition of Unactivated Nitriles to α,β-Unsaturated Ketones
Kartick Dey, Akhanda Gorai, Katarzyna Młodzikowska‐Pieńko, Natalia Fridman, Idan Avigdori, Renana Gershoni‐Poranne, and Graham de Ruiter
Read More51. ACS. Catal. 2025, 15, 5370-5377
Z-Selective Semihydrogenation of Alkynes Catalyzed by a Co(I)PCNHCP Pincer Complex: A Simple, Fast, and Practical Methodology
Tofayel Sheikh Mohammad, Pavel Sakharov, Sakthi Raje, and Graham de Ruiter
Read More50. Nat. Chem. 2025, 17, 215-225
Asymmetric Dearomative Single-Atom Skeletal Editing of Indoles and Pyrroles
Xiaolong Zhang, Qingmin Song, Shaopeng Liu, Paramasivam Sivaguru, Zhaohong Liu, Yong Yang, Yongyue Ning, Edward A Anderson, Graham de Ruiter, and Xihe Bi
Read More49. Angew. Chem. Int. Ed. 2024, 63, e202408220
Rhodium-Catalyzed Asymmetric Cyclopropanation of Indoles with N-Triftosylhydrazones
Caicai He, Wei Song, Dandan Wei, Wei Zhao, Qianfei Yu, Jiaqi Tang, Yongquan Ning, Karunanidhi Murali, Paramasivam Sivaguru, Graham de Ruiter, and Xihe Bi
Read More202448. Nat. Commum., 2024, 15, 9998
Halogencarbene-Free Ciamician-Dennstedt Single-Atom Skeletal Editing
Shaopeng Liu, Yong Yang, Qingmin Song, Zhaohong Liu, Paramasivam Sivaguru, Yifan Zhang, Graham de Ruiter, Edward A Anderson, and Xihe Bi
Read More47. JACS Au, 2024, 4, 4234-4248
N2 Dissociation vs Reversible 1,2-Methyl Migration in PCNHCP Cobalt(I) Complexes in the Stereoselective Isomerization (E/Z) of Allyl Ethers
Sakthi Raje, Subhash Garhwal, Katarzyna Młodzikowska-Pieńko, Tofayel Sheikh Mohammad, Ron Raphaeli, Natalia Fridman, Linda JW Shimon, Renana Gershoni-Poranne, and Graham de Ruiter
Read More46. Angew. Chem. Int. Ed. 2024, 63, e202401359
Controllable Skeletal and Peripheral Editing of Pyrroles with Vinylcarbenes
Yong Yang, Qingmin Song, Paramasivam Sivaguru, Zhaohong Liu, Dan Shi, Tian Tian, Graham de Ruiter, and Xihe Bi
Read More45. Org. Lett. 2024, 26, 4173-4177
Chemoselective Hydrogenation of α, β-Unsaturated Ketones Catalyzed by a Manganese (I) Hydride Complex
Kartick Dey and Graham de Ruiter
Read More44. Organometallics, 43, 817-828
Enantioselective Hydroboration of Styrenes with Markovnikov Selectivity Catalyzed by a Rhodium (I)-NHC Complex
Kartick Dey, Zeqing Chen, Natalia Fridman, and Graham de Ruiter
Read More43. J. Org. Chem., 2024, 89, 4319-4325
A Neutral PCNHCP Co(I)–Me Pincer Complex as a Catalyst for N-Allylic Isomerization with a Broad Substrate Scope
Sakthi Raje, Tofayel Sheikh Mohammad, and Graham de Ruiter
Read More42. Chem. Eur. J. 2024, 30, e202304227
Silver‐Catalyzed Dearomative Skeletal Editing of Indazoles by Donor Carbene Insertion
Linxuan Li, Hongzhu Chen, Menglin Liu, Qingwen Zhu, Hongru Zhang, Graham de Ruiter, and Xihe Bi
Read More41. JACS Au, 2024, 4, 344-368
Redox Processes Involving Oxygen: The Surprising Influence of Redox-Inactive Lewis Acids
Davide Lionetti, Sandy Suseno, Angela A Shiau, Graham de Ruiter, and Theodor Agapie
Read More40. Angew. Chem. Int. Ed. 2024, 63, e202313807
Dearomative Insertion of Fluoroalkyl carbenes Into Azoles Leading to Fluoroalkyl Heterocycles with a Quaternary Center
Linxuan Li, Yongquan Ning, Hongzhu Chen, Yongyue Ning, Paramasivam Sivaguru, Peiqiu Liao, Qingwen Zhu, Yong Ji, Graham de Ruiter, and Xihe Bi
Read More39. Chem. Comm. 2023,59, 426-429
Formation of Distinct Iron Hydrides via Mechanistic Divergence in Directed C–H Bond Activation of Aryl Ketones, Esters and Amides.
Subhash Garhwal, Jatin Panda, Natalia Fridman, Amir Karton, and Graham de Ruiter
Read More202338. Organometallics, 2023, 42, 1, 62–71
α-Methylation of Ketones and Indoles Catalyzed by a Manganese(I) PCNHCP Pincer Complex with Methanol as a C1 Source
Ranjeesh Thenarukandiyil, Rohit Kamte, Subhash Garhwal, Philipp Effnert, Natalia Fridman, and Graham de Ruiter
Read More37. Chem. Commun, 2022 58, 11563-11566
Cobalt-Catalyzed Cross-Coupling of Umpolung Carbonyls with Alkyl Halides Under Mild Conditions
Ruofei Cheng, Graham de Ruiter, and Chao-Jun Li
Read More202236. Inorg. Chem. 2021, 60, 18296–18306
Extensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Study
Ranjeesh Thenarukandiyil, Eno Peanurk, Anthony Wong, Natalia Fridman, Amir Karton, Raanan Carmieli, Gabriel Menard, Renana Gershoni-Poranne, and Graham de Ruiter
View Publication202135. J. Mater. Chem. C,. 2021, 9, 11569-11587
Molecular Functionalization of 2D Materials: From Atomically Planar 2D Architectures to Off-Plane 3D Functional Materials
Adam Brill, Elad Koren, and Graham de Ruiter
View Publication34. Chem Catalysis. 2021, 1, 631-647
Part per Million Levels of an Anionic Iron Hydride Complex Catalyzes Selective Alkene Isomerization via Two-State Reactivity
Subhash Garhwal, Alexander Kaushansky, Natalia Fridman, and Graham de Ruiter
View Publication33. ACS Appl. Mater. Interfaces. 2021, 13, 32590–32597
Modulating the Optoelectronic Properties of MoS2 by Highly Oriented Dipole-Generating Monolayers
Adam Brill, Alonit Kafri, Pranab K. Mohapatra, Ariel Ismach, Graham de Ruiter, and Elad Koren
View Publication32. ACS Appl. Mater. Interfaces. 2021, 13, 10271–10278
Dipole-Induced Raman Enhancement Using Non-covalent Azobenzene Functionalized Self-Assembled Monolayers on Graphene Terraces
Adam R. Brill, Santu Biswas, Maytal Caspary Toroker, Graham de Ruiter, and Elad Koren
View Publication31. Chem. Asian. J. 2021, 16, 999-106
Hydroboration of Nitriles, Esters, and Carbonates Catalyzed by Simple Earth-Abundant Metal Triflate Salts
Ranjeesh Thenarukandiyil, Linda J. W. Shimon, and Graham de Ruiter
View Publication30. Inorg. Chem. 2021, 60, 494-504
Manganese-Catalyzed Hydroboration of Terminal Olefins and Metal-Dependent Selectivity in Internal Olefin Isomerization–Hydroboration
Subhash Garhwal, Asja A. Kroeger, Ranjeesh Thenarukandiyil, Natalia Fridman, Amir Karton, and Graham de Ruiter
View Publication29. J. Am. Chem. Soc. 2020, 142, 17131-171395
Facile H/D Exchange at (Hetero)Aromatic Hydrocarbons Catalyzed by a Stable Trans-Dihydride N-Heterocyclic Carbene (NHC) Iron Complex
Subhash Garhwal, Alexander Kaushansky, Natalia Fridman, Linda J. W. Shimon, and Graham de Ruiter
View Publication202028. Inorg. Chem. 2020, 59, 13817-13821
Z-Selective Alkyne Functionalization Catalyzed by a Trans-Dihydride N-Heterocyclic Carbene (NHC) Iron Complex
Subhash Garhwal, Natalia Fridman, and Graham de Ruiter
View Publication27. ACS. Appl. Mater. Interfaces. 2020, 12, 33941-33949
Formation of Highly Ordered Self-Assembled Monolayers on 2D Materials via Non-Covalent Functionalization
Adam R. Brill, Mohan Kumar Kuntumalla, Graham de Ruiter, and Elad Koren
View Publication26. Chem. Eur. J. 2020, 26, 2333-2337
Direct Asymmetric Hydrogenation and Dynamic Kinetic Resolution of Aryl Ketones Catalyzed by an Iridium-NHC Exhibiting High Enantio- and Diastereoselectivity
Chinna Ayya Swamy P., Andrii Varenikov, and Graham de Ruiter
View Publication25. Organometallics. 2020, 247-257
Chiral Imidazo[1,5-a]pyridineOxazolines: A Versatile Family of NHC Ligands for the Highly Enantioselective Hydrosilylation of Ketones
Chinna Ayya Swamy P., Andrii Varenikov, and Graham de Ruiter
View Publication24. ACS Appl. Mater. Interfaces. 2019, 11, 22858-22868
On-Surface Self-Assembly of Stimuli-Responsive Metallo-Organic Films: Automated Ultrasonic Spray-Coating and Electrochromic Devices
Naveen Malik, Netal Elool Dov, Graham de Ruiter, Michal Lahav, and Milko E. van der Boom
View Publication201923. J. Am. Chem. Soc. 2018, 140, 8162–8171
Sorting of Molecular Building Blocks from Solution to Surface
Hodaya Keisar, Graham de Ruiter, Aldrik Velders, Petr Milko, Antonino Gulino, Guannadi Evmenenko, Linda Shimon, Yael Diskin-Posner, Michal Lahav, and Milko van der Boom
View Publication201822. Chem. Eur. J. 2017, 45, 10744-10749
Selectivity of C−H vs. C−F Bond Oxygenation by Homo- and Heterometallic Fe4, Fe3Mn, and Mn4 Clusters
Graham de Ruiter, Kurtis M. Carsch, Michael K. Takase, and Theodor Agapie
View Publication201721. Inorg. Chem. 2017, 56, 9044-9054
Intramolecular C–H and C–F Bond Oxygenation by Site-Differentiated Tetranuclear Manganese Models of the OEC
Kurtis M. Carsch, Graham de Ruiter, and Theodor Agapie
View Publication20. Angew. Chem. Int. Ed. 2017, 56, 4772-4776
Accelerated Oxygen Atom Transfer and C−H Bond Oxygenation by Remote Redox Changes in Fe3Mn-Iodosobenzene Adducts
Graham de Ruiter, Kurtis M. Carsch, Sheraz Gul, Ruchira Chatterjee, Niklas B. Thompson, Michael K. Takase, Yunko Yano, and Theodor Agapie
View Publication19. J. Am. Chem. Soc. 2016, 138, 16398-16406.
Light-Induced Conversion of Chemical Permeability to Enhance Electron and Molecular Transfer in Nanoscale Assemblies
Renata Balgley, Graham de Ruiter, Guennadi Evmenenko, Tatyana Bendikov, Michal Lahav, and Milko E. van der Boom
View Publication201618. J. Am. Chem. Soc. 2016, 138, 5008-5011
A Trans-Hyponitrite Intermediate in the Reductive Coupling and Deoxygenation of Nitric Oxide by a Tricopper-Lewis Acid Complex
Davide Lionetti, Graham de Ruiter, and Theodor Agapie
View Publication17. J. Am. Chem. Soc. 2016, 138, 1486–1489
Intramolecular C–H and C–F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron Complexes
Graham de Ruiter, Niklas B. Thompson, and Theodor Agapie
View Publication16. J. Am. Chem. Soc. 2015, 137, 14094–14106
Nitric Oxide Activation by Distal Redox Modulation in Tetranuclear Iron Nitrosyl Complexes
Graham de Ruiter, Niklas B. Thompson, Davide Lionetti, and Theodor Agapie
View Publication201515. Acc. Chem. Res. 2014, 47, 3407-3417.
Pyridine and Metal Coordination Chemistry: Versatile Tools for Molecular Assembly Formation on Surfaces
Graham de Ruiter, Michal Lahav, and Milko E. van der Boom
View Publication201414. J. Am. Chem. Soc. 2013, 135, 16533-16544
Composite Molecular Assemblies: Nanoscale Control and Spectroelectrochemical Diversity
Graham de Ruiter, Michal Lahav, Guennadi Evmenenko, Pulak Dutta, Domenico A. Christaldi, Antonino Gulino, and Milko E. van der Boom
View Publication201313. Chem. Eur. J. 2013, 79, 8821-8831
Coordination Based Assemblies of Oligofurans and Oligothiophenes
Adva Hayoun-Barak, Graham de Ruiter, Michal Lahav, Sagar Sharma, Ori Gidron, Guennadi Evmenenko, Pulak Dutta, Michael Bendikov, and Milko E. van der Boom
View Publication12. Angew. Chem. Int. Ed. 2013, 52, 704-709
Sequence Dependent Assembly to Control Molecular Interface Properties
Graham de Ruiter, Michal Lahav, Hodaya Keisar, and Milko E. van der Boom
View Publication11. Angew. Chem. Int. Ed. 2012, 51, 8598-8601
Orthogonal Addressable Monolayers for Integrating Molecular Logic
Graham de Ruiter and Milko E. van der Boom
View Publication201210. J. Mater. Chem. C. 2011, 21, 17575-17581
Sequential Logic and Random Access Memory (RAM): A Molecular Approach
Graham de Ruiter and Milko E. van der Boom
View Publication201109. Acc. Chem. Res. 2011, 44, 563-573
Surface Confined Assemblies and Polymers for Molecular Logic
Graham de Ruiter and Milko E. van der Boom
View Publication08. ACS Appl. Mater. Interfaces. 2010, 2, 3578-3585
Polymeric Memory Elements and Logic Circuits that Store Multiple Bit States
Graham de Ruiter, Yair H. Wijsboom, Noa Oded, and Milko E. van der Boom
View Publication201007. J. Am. Chem. Soc. 2010, 132, 9295-9297
Linear vs. Exponential Formation of Molecular-Based Assemblies
Joyanta Choudhury, Revital Kaminker, Leila Motiei, Graham de Ruiter, Michael Morozov, Fabio Lupo, Antonino Gulino, and Milko E. van der Boom
View Publication06. Angew. Chem. Int. Ed. 2010, 49, 4780-4783
Electrical Addressable Multi-State Volatile Memory with Flip-Flop and Flip-Flap-Flop Logic Circuits on a Solid Support
Graham de Ruiter, Leila Motiei, Joyanta Choudhury, Noa Oded, and Milko E. van der Boom
View Publication05. Angew. Chem. Int. Ed. 2010, 49, 169-172
Sequential Logic Operations with Surface-Confined Polypyridyl Complexes Displaying Molecular Random Access Memory Features
Graham de Ruiter, Elisabetha Tartakovsky, Noa Oded, and Milko E. van der Boom
View Publication04. Dalton Trans. 2010, 39, 4991-4997
High Nuclearity Manganese(III) Compounds Containing Phenol-Pyrazole Ligands : the Influence of the Ligand on the Core Geometry
Marta Viciano-Chumillas, Graham de Ruiter, Stefania Tanase, Jan M. M. Smits, Rene de Gelder, Ilpo Mutikainen, Urho Turpeinen, L. Jos de Jongh, and Jan Reedijk
View Publication03. J. Am. Chem. Soc. 2008, 130, 2744-2745
Selective Optical Recognition and Quantification of Parts Per Million Levels of Cr6+ in Aqueous and Organic Media by Immobilized Polypyridyl Complexes on Glass
Graham de Ruiter, Tarkeshwar Gupta, and Milko E. van der Boom
View Publication200802. Inorg. Chem. Commun. 2008, 11, 787-790.
The System Iron(II)/mpzbpy Mediates the H2O2 Oxidation of Cyclohexane and Cyclooctene and the Aerobic Cleavage of Ascorbic Acid to Oxalate
Graham de Ruiter, José Sanchez Costa, Kristian Lappalainen, Olivier Roubeau, Patrick Gamez, and Jan Reedijk
View Publication01. Inorg. Chem. 2007, 46, 4079-4089.
Remarkable Steric Effects and the Influence of Monodentate Axial Ligands L on the Spin-Crossover Properties of Trans-[FeII(N4 Ligand)L] Complexes
José Sanchez Costa, Kristian Lappalainen, Graham de Ruiter, Manuel Quesada, Jinkui Tang, Ilpo Mutikainen, Urho Turpeinen, C. Matthias Grunert, Phillip Gütlich, Hanane Zhor Lazar, Jean-François Létard, Patrick Gamez, and Jan Reedijk
View Publication